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  • Utilization of Ion Accelerators for Studying and Modelling of Radiation Induced Defects in Semiconductors and Insulators

    Closed for Proposals

    Project Type

    Coordinated Research Project

    Project Code

    F11016

    CRP

    1749

    Approved Date

    20/09/2011

    Project Status

    Closed

    Start Date

    14/12/2011

    Expected End Date

    02/11/2016

    Completed Date

    02/11/2016

    Description

    There are many fields of research and technology which require the use of electronic materials and devices working in harsh radiation environments, for example, in high energy physics facilities, remote control systems in nuclear reactors, radiation therapy systems, radiation detectors and the aerospace sector. One needs to consider both the immediate effects of radiation induced damage on material and device electrical properties and also the longer term accumulation of damage which can limit the useful lifetime. While the effect of radiation induced defects on properties of semiconducting and insulating materials and devices has been studied for 50 years, there are still significant gaps in the understanding of what types of defects are formed, how they can be detected and their effects on electrical and structural properties. This proposal for a Coordinated Research Project (CRP) reflects the needs of Member States in the domain of radiation effects of electronic materials, with the aim of enhancing the present understanding of the types and effects of the different defects produced using accelerator-based irradiation and measurements combined with theoretical modelling and simulation. The objectives of the CRP are to enhance the capabilities of the interested Member States by facilitating their collective efforts to use accelerator-based light and heavy ion irradiation of electronic materials in conjunction with all available advanced characterization techniques to gain a deeper understanding of how different types of radiation influences the short and long term electronic properties of materials and devices, leading to an improved radiation resistance.

    Objectives

    Improved understanding of how radiation induced defects form in semiconductors and insulators, leading to better understanding of how they degrade or improve electrical properties of materials and devices, and improved performance of electronic devices in extreme and harsh radiation environments.

    Specific Objectives

    Deeper theoretical knowledge and experimental data on defects created by light and heavy ions; in terms of their type, density and effect on fundamental electronic properties of semiconductors and insulators.

    Impact

    The CRP results provided the very first protocol and the only one is available so far to evaluate the radiation hardness of semiconductor materials and devices under any kind of MeV ion, which is important to all research communities involving the use of these ions, such as in ion beam analysis, ion beam modification of materials, radiation effects in insulators. The experimental and theoretical approach can be used by all laboratories to provide data independent of the experimental setup concerning radiation hardness.

    The new results will improve the ability of the ion beam accelerator community to characterize the response of semiconductors detectors to cumulative irradiation of all forms, and to better predict their life-time.

    IBIC technique has proven to be a very powerful tool for the functional characterization of semiconductor devices; it has been extensively applied and optimised by expert groups (ANSTO, RBI, SANDIA, NUS), adopted for the first time at CNA and used for the first time at UniLe to map the CCE efficiency of diamond diodes.

    New experimental techniques and set-ups have been installed and used for material characterization: notably Transient Current Technique (TCT) at UniDe and UniS, Alpha Particle and Heavy Ion Charge Transient (APQTS and HIQTS, respectively) at JAEA, a new high resolution IBIC system at NUS.

    Enhanced skills in device simulations have been acquired at UniDe by using SILVACO simulation software to model the electronic features of the Si diodes under study and at SANDIA with ATLAS TCAD software to model the IBIC processes.
    The transport modelling developed during the CRP has been exploited by UniTo and NUS for the interpretation of experiments aimed to fabricate micro- and nano- structures in porous silicon.
    A new deterministic single ion implanter has been designed at UniLe mainly devoted to the controlled creation of NV centers in diamond. Noteworthy, a new high resolution IBIC technique based on ion tracks in mica foils has been investigated, which can lead to a spot size below 100 nm.. This is a breakthrough for non-developed countries in order to setup a cheap ion nanobeam for different types of experiments with high reliability.

    All the participants agreed that the most important benefit from this CRP is the expanded network of collaborating researchers and institutions. The reinforcement of already existing collaborations and the activation of new ones (among them, the new collaboration among MNA, UniHe, UniS, CNA, JAEA, RBI and ANSTO on ion/electron/neutron/ion irradiated SiC diodes or between UniDe and NUS for diode fabrication and educational activities), has led to a generally improvement of the expertise and the capabilities of the CRP participants.

    The achievement of the main CRP objectives, the dissemination of new experimental techniques and theoretical model have contributed to improve the competiveness of CRP members in applications for national and international grants, as demonstrated for example by grants to JAEA, in collaboration with RBI, from the Japan Society for the Promotion of Science for the development of diamond detectors, to MNA for the Semiconductor Nuclear Radiation Detector Laboratory from the Malaysian Nuclear Agency and to CNA to study the feasibility of Fast-Ion Loss Detector for ITER based on SiC diodes.

    Relevance

    The CRP resulted new dataset, improved measurement methods and data treatments available freely for the whole IBA community and materials scientists.
    The results are being utilized in IAEA projects and international collaborations.

    The work implemented within this CRP and results achieved are fully relevant to the IAEA programme as:
    1) Utilization and further development of ion beam accelerator-based techniques for irradiation and analysis;
    2) Improved understanding of material modification and hardness;
    3) Improved prediction of life-time of semiconductor detectors used in radiation harsh environments;
    4) Improved understanding of ion-matter interactions including theoretical modelling;
    5) Knowledge transfer, capacity building and networking.

    CRP Publications

    Croatia
    international scientific publication
    2013
    Natko Skukan, Veljko Grilj, Milko Jak?ic, CVD diamond as a position sensitive detector using charge carrier transition time, Nucl. Instr. Math. B306 (2013) 186-190
    Singapore/Italy
    international scientific publication
    2013
    Defect enhanced funneling of diffusion current in silicon. S. Azimi, Z. Y. Dang, J. Song, M. B. H. Breese, E. Vittone, and J. Forneris, APPL. PHYSICS LETTERS 102, 042102 (2013).
    Singapore/Italy
    international scientific publication
    2014
    Enhanced electrochemical etching of ion irradiated silicon by localized amorphization. Z. Y. Dang, M. B. H. Breese, Y. Lin, E. S. Tok, and E. Vittone, APPL. PHYSICS LETTERS 104, 192108 (2014).
    Malaysia
    national scientific publication
    2013
    Yusof Abdullah, Mohd Reusmaazran Yusof, Megat Harun Al Rashid Megat Ahmad, Hafizal Yazid, Abdul Aziz Mohamed, Norazila Mat Zali and Ishak Mansor, Effect of 3.0 MeV electron irradiation on 4H-SiC wafer properties. Nuclear Science Journal of Malaysia (e-JSNM), 2013, Vol. 25 (1), ISSN: 2232-0946: 9-16.
    Singapore
    international scientific publication
    2014
    Integration of nano-scale components and supports in micromachined 3D silicon structures. J. Song, S. Azimi, Z. Y. Dang and M. B. H. Breese. J. Micromech. Microeng. 24 045008 (2014).
    Croatia/Australia/Italy
    international scientific publication
    2014
    Z. Pastuovic, I. Capan, R. Siegele, R. Jacimovic, J. Forneris, D.D. Cohen, E. Vittone,Generation of vacancy cluster-related defects during single MeV silicon ion implantation of silicon, B332 (2014) 298.
    Italy/Croatia
    international scientific publication
    2014
    J. Forneris, M. Jaksic, Z. Pastuovic, E. Vittone, A Monte Carlo software for the 1-dimensional simulation of IBIC experiments, NIM B 332 (2014) 257.
    Croatia/Italy/Australia/USA
    Annual report
    2013
    Z. Pastuovic, E. Vittone, R. Siegele, I. Capan, G. Vizkelethy, D. Cohen, M. Jaksic, “Single-ion induced defects in semiconductors: implantation, characterisation and modelling", ANSTO Research Selections (2013) 34.
    Italy
    computer code and training material
    2014
    Monte Carlo based software with graphical user interface for the simulation of IBIC experiments developed by Jacopo Forneris is available on University of Torino and the IAEA Accelerator Knowledge Portal websites.
    Singapore
    international scientific publication
    2014
    Fabrication of silicon molds with multi-level, non-planar, micro- and nano-scale features. S. Azimi, Z. Y. Dang, K. Ansari, M. B. H. Breese, Nanotechnology 25 (2014) 375301.
    Spain
    international scientific publication
    2014
    J. García López and M.C. Jiménez-Ramos, “Charge collection efficiency degradationon Si diodes irradiated with high energy protons “ Nucl. Instr. Meth. B 332 (2014) 220-223.
    Croatia/Japan
    international scientific publication
    2013
    V Grilj, N Skukan, M Pomorski, W Kada, N Iwamoto, T. Kamiya, T. Ohshima, M. Jak?ic, An ultra-thin diamond membrane as a transmission particle detector and vacuum window for external microbeams, Applied Physics Letters, 103 (2013) 243106
    Italy/Croatia
    international scientific publication
    2013
    J. Forneris, V. Grilj, M. Jak?ic, A. Lo Giudice, P. Olivero, F. Picollo, N. Skukan, C. Verona, G. Verona-Rinati, E. Vittone, IBIC characterization of an ion-beam-micromachined multi-electrode diamond detector, Nucl. Instr. Meth. B306 (2013) 181-185.

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