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  • Global Monitoring of Nitrogen Isotopes in Atmospheric Waters

    Closed for proposals

    Project Type

    Coordinated Research Project

    Project Code

    F32008

    CRP

    2209

    Approved Date

    7 December 2017

    Status

    Closed

    Start Date

    28 May 2018

    Expected End Date

    30 June 2023

    Completed Date

    7 March 2023

    Participating Countries

    Australia
    Belgium
    Brazil
    China
    Costa Rica
    Cuba
    Estonia
    Ghana
    Greece
    India
    Italy
    Kenya
    Singapore
    Sri Lanka
    Thailand
    United States of America
    Viet Nam

    Description

    The increasing production of food and energy worldwide has multiplied today's anthropogenic emissions of nitrogen compounds in the atmosphere, which are transported and deposited through precipitation on the terrestrial and aquatic systems. Disruption of N-balance, eutrophication in rivers and lakes, and stream acidification are a few of the negative consequences, when N-deposition exceeds the remediation capacity or critical load of the aquatic system. Environmental isotopes have been widely used not only to assess hydrological processes, but also to address water quality issues, such as nitrogen pollution. This CRP aims to determine the spatio-temporal distribution of nitrogen isotopes in precipitation as a potential source of nitrogen pollution of water resources, especially of aquatic systems sensitive to eutrophication stressors. This CRP aims to combine N-isotopes with atmospheric chemistry and hydrometeorological techniques to better understand wet deposition processes and to characterize the origin of inorganic nitrogen loadings. Overall, the CRP will aim at improving the capability and expertise among participating Member States in the use of environmental isotopes to assess impacts of nitrogen wet deposition on water quality and ecosystems.

    Objectives

    To improve capability and expertise among Member States in the use of environmental isotopes to better assess impacts of nitrogen wet deposition on water quality.

    Specific objectives

    Explore the use of N-isotopes in precipitation networks in order to determine spatial patterns of N-isotope values that can be used to determine the relative contribution of nitrogen wet deposition in the degradation of water systems.

    Improve the application of N-isotopes combined with other isotope and chemistry substances to better define the origin of nitrogen in precipitation and evaluate the impact of nitrogen wet deposition on water resources and ecosystems.

    Assess and improve the understanding and interpretation of nitrogen transformations related to wet deposition.

    Explore the use of N-isotopes in precipitation networks in order to determine spatial patterns of N-isotope values that can be used to determine the relative contribution of nitrogen wet deposition in the degradation of water systems.

    Improve the application of N-isotopes combined with other isotope and chemistry substances to better define the origin of nitrogen in precipitation and evaluate the impact of nitrogen wet deposition on water resources and ecosystems.

    Assess and improve the understanding and interpretation of nitrogen transformations related to wet deposition.

    Impact

    CRP has a significant positive impact on the development of the nuclear application to support water quality studies. Particularly, Member States tested and applied routine use of environmental isotopes for the assessment of nitrogen wet deposition that can impact surface water and pose an eutrophication. TECDOC will provide a continuous guidance on the sampling, analysis and data interpretation and ensure the CRP outputs sustainability. Tested method was discussed and implemented in the TC projects in Latin America (Costa Rica) and Africa (Mauritius). Additionally, method, approach and data derived from the CRP were used in the Master and PhD studies in developing countries.

    Relevance

    CRP advanced understanding of possible environmental and anthropogenic impacts of nitrogen deposition on water resources for optimal water resources management and remediation strategies.

    CRP Publications

    Type

    Article

    Year

    2021

    Publication URL

    https://www.sciencedirect.com/science/article/pii/S004565352102275X

    Description

    Fresh and aged PM2.5 and their ion composition in rural and urban atmospheres of Northern Thailand in relation to source identification

    Country/Organization

    Thailand

    Type

    Article

    Year

    2021

    Publication URL

    https://www.nature.com/articles/s41467-020-20356-0

    Description

    Important contributions of non-fossil fuel nitrogen oxides emissions

    Country/Organization

    China

    Type

    Short Communication

    Year

    2020

    Description

    Nitrogen isotope differences between atmospheric nitrate and corresponding nitrogen oxides: A new constraint using oxygen isotopes

    Country/Organization

    China

    Type

    Article

    Year

    2022

    Publication URL

    https://doi.org/10.1016/j.atmosres.2021.105971

    Description

    Isotopic composition (d15N, d18O) of nitrate in high-frequency precipitation events differentiate atmospheric processes and anthropogenic NOx emissions

    Country/Organization

    IAEA

    Type

    Article

    Year

    2020

    Publication URL

    https://pubs.acs.org/doi/10.1021/acs.estlett.0c00105

    Description

    Nitrogen Isotope Differences between Major Atmospheric NOy Species: Implications for Transformation and Deposition Processes

    Country/Organization

    China

    Type

    Article

    Year

    2020

    Publication URL

    https://www.sciencedirect.com/science/article/pii/S0045653519322635

    Description

    Nitrate sources and formation of rainwater constrained by dual isotopes in Southeast Asia: Example from Singapore

    Country/Organization

    Singapore

    Type

    Article

    Year

    2021

    Publication URL

    https://doi.org/10.1016/j.atmosenv.2021.118740

    Description

    Distinguishing in-cloud and below-cloud short and distal N-sources from high-temporal resolution seasonal nitrate and ammonium deposition in Vienna, Austria.

    Country/Organization

    IAEA

    Type

    Article

    Year

    2022

    Publication URL

    https://doi.org/10.1016/j.atmosenv.2022.119300

    Description

    Imprints of anthropogenic air pollution sources on nitrate isotopes in precipitation in a tropical metropolitan area

    Country/Organization

    Brazil

    Type

    Article

    Year

    2021

    Publication URL

    https://www.sciencedirect.com/science/article/pii/S004565352102275X

    Description

    Fresh and aged PM2.5 and their ion composition in rural and urban atmospheres of Northern Thailand in relation to source identification

    Country/Organization

    Thailand

    Type

    Article

    Year

    2020

    Publication URL

    https://pubs.acs.org/doi/10.1021/acs.estlett.0c00105

    Description

    Nitrogen Isotope Differences between Major Atmospheric NOy Species: Implications for Transformation and Deposition Processes

    Country/Organization

    China

    Type

    Short Communication

    Year

    2020

    Description

    Nitrogen isotope differences between atmospheric nitrate and corresponding nitrogen oxides: A new constraint using oxygen isotopes

    Country/Organization

    China

    Type

    Article

    Year

    2021

    Publication URL

    https://www.nature.com/articles/s41467-020-20356-0

    Description

    Important contributions of non-fossil fuel nitrogen oxides emissions

    Country/Organization

    China

    Type

    Article

    Year

    2020

    Publication URL

    https://www.sciencedirect.com/science/article/pii/S0045653519322635

    Description

    Nitrate sources and formation of rainwater constrained by dual isotopes in Southeast Asia: Example from Singapore

    Country/Organization

    Singapore

    Type

    Article

    Year

    2021

    Publication URL

    https://link.springer.com/article/10.1007/s11356-021-15327-x

    Description

    Stable isotopic characterization of nitrate wet deposition in the tropical urban atmosphere of Costa Rica

    Country/Organization

    Costa Rica

    Type

    Article

    Year

    2023

    Publication URL

    https://doi.org/10.1080/10256016.2023.2177649

    Description

    Nitrate isotopes ( d15N, d18O) in precipitation: best practices from an international coordinated research project

    Country/Organization

    IAEA

    Type

    Article

    Year

    2021

    Publication URL

    https://link.springer.com/article/10.1007/s11356-021-15327-x

    Description

    Stable isotopic characterization of nitrate wet deposition in the tropical urban atmosphere of Costa Rica

    Country/Organization

    Costa Rica

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