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  • Radiation Curing of Composites for Enhancing their Features and Utility in Health Care and Industry

    Closed for Proposals

    Project Type

    Coordinated Research Project

    Project Code

    F22051

    CRP

    1783

    Approved Date

    15 November 2010

    Project Status

    Closed

    Start Date

    14 March 2011

    Expected End Date

    14 March 2015

    Completed Date

    3 November 2015

    Description

    Composite materials combine properties of the individual components in a synergetic manner to produce a variety of materials in an efficient and cost effective manner. Thus, composite materials today are being used in various applications from sports equipment, automotive and aerospace industries to food packaging and artificial organs. Materials reinforced with nanoscale components are adding new dimensions to composite materials and enable further major improvements in functional and structural properties. The incorporation of only a few percent of nano-sized particles can make dramatic property changes that may result in sensing, actualization or self-healing properties of the resulting composite. Several major issues need to be addressed to utilize the full potential of such nanofillers, and among them: (i) incompatibility or weak interfacial bonding between the matrix and the nanoscale component, and (ii) agglomeration of nanosized component during processing resulting in inhomogeneous distribution. According to the results of ongoing investigation and products preparation in several Member States institutions, radiation technology offers a way of overcoming these challenges by grafting of appropriate monomers/polymers onto the nanofiller surface thereby fixing their morphology and at the same time making them compatible with the host polymer. Additionally, radiation techniques offer the possibility for simultaneous synthesis of the nanoparticle component and crosslinking of the matrix of the composite that is not possible to achieve by other techniques. With the availability of lower cost self-shielded low energy electron beam accelerators, this process is increasingly becoming available for developing member states. In order to use the advantages of radiation techniques and address the needs of Member States for producing advanced composite materials, this CRP has been formulated based on the recommendations of a Consultant’s Meeting. The CRP aims to support MS to develop methodologies and protocols for new abrasion resistant coating formulations, radiation curable nano-composites from natural polymers, new biodegradable packaging materials suitable for radiation sterilization, and new methods to modify surface characteristic of nano-sized materials to enhance polymer fillers interaction. This CRP will provide a forum for knowledge and technology transfer among the participating institutions, as well as to promote early involvement of developing countries in knowledge-intensive R&D programs to enhance their level of competence and confidence and promote the local spin-off initiatives.

    Objectives

    To enhance member States capability in the use of radiation technology for production of nano-composites with enhanced quality, safety, stability and functionality for advanced applications.

    Specific Objectives

    To assess the methods to modify surface characteristic of nano-sized materials to enhance polymer fillers interaction

    To develop radiation curable nano-composites from natural polymers

    To harmonize preparations and specifications of new biodegradable packaging materials suitable for radiation sterilization

    To standardize formulations of new scratch and abrasion resistant coatings with enhanced surface finishing

    Impact

    The participants have developed numerous protocols for the preparation of nanocomposites that would not have been there without the joint effort under this CRP, and which are being transferred into new products. New preparation methods have been discovered that resulted in improved characteristics of the final products enabling new applications. Besides the collaboration towards the objectives of the CRP, strong collaboration and a network had been established that is in place and under a strategic partnership projects within the framework of EU Erasmus program is organizing and delivering training and teaching programme in enhancing development and transfer of knowledge of application of ionizing radiation in materials processing. The CRP also had an impact on the new CRP entitled: Application of Radiation Technology for the Development of Advanced Packaging Materials for Food Products", which benefits from the packaging materials developed under this completed CRP. Additionally, the journal articles published under this CRP enriched the knowledge of the scientific community worldwide.

    Relevance

    The CRP in line with the objective of the project 2.5.2.2, to enhance Member State capabilities in applying radiation technology for advanced materials development and processing natural polymers into value added products, and it is relevant to Member States programmes and projects.

    CRP Publications

    Canada
    International scientific journal
    2012
    Akter, N., Khan, R., Salmieri, S., Sharmin, N., Dussault, D., Lacroix, M. Fabrication and mechanical characterization of biodegradable and synthetic polymeric films: Effect of ?-irradiation. Rad. Phys. Chem., 81 (2012) 995-998.
    Canada/Egypt
    International scientific journal
    2010
    Senna M.M., Salmieri S, El-Naggar AW, Safrany A, Lacroix M. Improving the compatibility of Zein / Polyvinyl alcohol blends by gamma irradiation and graft copolymerization of acrylic acid. J. Agric. Food Chem., 58 (2010) 4470-4476.
    India
    International scientific journal
    2014
    CHAUDHARI, C. V., K. A. DUBEY, Y. K. BHARDWAJ AND S. SABHARWAL, Radiation processed styrene-butadiene rubber/ethylene-propylene diene rubber/multiple-walled carbon nanotubes nanocomposites: Effect of MWNT addition on solvent permeability behavior, Journal of Macromolecular Science, Part B: Physics 51(5)(2014) 839-859
    Pakistan
    International scientific journal
    2013
    YASIN, T., NISAR, M., SHAFIQ, M., NHO, Y.C., AHMAD, R. “Influence of Sepiolite and Electron Beam Irradiation on the Structural and Physicochemical Properties of Polyethylene/Starch Nanocomposites”. Polym. Composites, 34/3 (2013) 408–416.
    india
    International scientific journal
    2014
    MAJJI, S., K. A. DUBEY, R. K. MONDAL, Y. K. BHARDWAJ AND S. ACHARYA, Development of Electron Beam Cross-Linked PDMS/PTFEM Composites with Low Coefficient of Friction and High Elastic Modulus, Polymer - Plastics Technology and Engineering 53(5) (2014) 435-441.
    Turkey
    International scientific journal
    2014
    BAKAR, A., GüVEN,O., ZEZIN, A.A., FELDMAN,V.I., “Controlling the size and distribution of copper nanoparticles in double and triple polymer-metal complexes by X-ray irradiation” Rad. Phys. Chem.,94(2014)62-65.
    USA/France
    International scientific journal
    2014
    FARAHANI,.M., CLOCHARD, M.C., GIFFORD, I., BARKATT, A. AND AL-SHEIKHLY, M., Differences in Fundamental Reaction Mechanisms between High and Low-LET in Recent Advancements and Applications of Ionizing Radiation, Rad. Phys. Chem., 105 (2014) 39–47.
    Canada
    International scientific journal
    2013
    Khan, R.A., Beck, S., Dussault, D., Salmieri, S., Bouchard, J., Lacroix, M. Mechanical and barrier properties of nanocrystalline cellulose reinforced poly (caprolactone) composites: effect of gamma radiation. J. Appl. Polymer Sc., 129 (2013) 3038-3046.
    Canada
    International scientific journal
    2012
    Khan, R., Dussault D., Salmieri, S., Safrany, A., Lacroix, M., Improvement of the mechanical and barrier properties of methylcellulose-based films by treatment with HEMA and silane monomers under gamma radiation. Rad. Phys. Chem., 81 (2012) 927-931.
    Serbia
    International scientific journal
    2014
    KRSTIC, J., SPASOJEVIC, J., RADOSAVLJEVIC, A., PERIC-GRUJIC, A., DJURIC, M., KACAREVIC-POPOVIC, Z., POPOVIC, S., In vitro silver ion release kinetics from nanosilver/poly(vinyl alcohol) hydrogels synthesized by gamma irradiation, J. Appl. Polym. Sci. 131 (2014) Article No. 40321.
    India
    International scientific journal
    2013
    SINHA, S. K., K. A. DUBEY, V. GROVER, P. SASTRY, Y. K. BHARDWAJ, L. PANICKER, A. K. TYAGI, P. A. MAHANWAR AND V. A. BAMBOLE, Selective interfacial localization in conducting polycaprolactam/ethylene vinyl acetate/carbon black composites, Polymer Composites 34(6) (2013) 912-919.
    Canada
    International scientific journal
    2012
    Khan, R., Salmieri, S., Dussault, D., Uribe-Calderon, J., Kamal, M.R., Safrany, A., Lacroix, M. Preparation, gamma-irradiation and thermo-mechanical characterization of chitosan loaded methylcellulose films. J. Polym. Environ. 20 (2012) 43-52
    Canada
    International scientific journal
    2012
    Sharmin, N., Khan, R., Dussault, D., Salmieri, S., Akter, N., Lacroix, M. Effectiveness of silane monomer and gamma radiation on chitosan films and PCL-based composites. Rad. Phys. Chem., 81 (2012) 932-935.
    Canada
    International scientific journal
    2012
    Huq, T., Khan, A., Dussault, D., Salmieri, S., Khan, R.A., Lacroix, M. Effect of ?-irradiation on the physico-chemical properties of alginate-based films and beads. Rad. Phys. Chem. 81 (2012) 945-48.
    Canada
    International scientific journal
    2014
    Lacroix, M., Khan, R., Senna, M., Sharmin, N., Salmieri, S., SAFRANY, A, Radiation grafting on natural films. Rad. Phys. Chem., 94 (2014) 88-92.
    Germany
    International scientific journal
    2014
    BAUER, F., DECKER, U., NAUMOV, S., RIEDEL, C. (2014). Photoinitiator-free UV curing and matting of acrylate-based nanocomposite coatings: Part 3. Progress in Organic Coatings 77 (2014) 1085-1094.
    Serbia
    International scientific journal
    2014
    KRSTIC, J., SPASOJEVIC, J., RADOSAVLJEVIC, A., SILJEGOVIC, M., KACAREVIC-POPOVIC, Z., Optical and structural properties of radiolytically in situ synthesized silver nanoparticles stabilized by chitosan/poly(vinyl alcohol) blends, Rad. Phys. Chem. 96 (2014) 158-166.
    Italy
    2012
    International scientific journal
    ALESSI S, SPINELLA A, CAPONETTI E, DISPENZA C, SPADARO G. Structural investigation of e-beam cured epoxy resins through solid state NMR. Radiat. Phys. Chem. 81 (2012) 1328-1331.
    Canada
    International scientific journal
    2012
    Sharmin, N., Khan, R.A., Salmieri, S., Dussault, D., Bouchard, J., Lacroix, M. Modification and characterization of biodegradable methylcellulose films with trimethylolpropane trimethacrylate (TMPTMA) by gamma radiation: effect of nanocrystalline cellulose. J. Agric. Food Chem., 60 (2012) 623-629.
    India
    International scientific journal
    2011
    DUBEY, K. A., Y. K. BHARDWAJ, C. V. CHAUDHARI, N. K. GOEL, S. SABHARWAL, K. RAJKUMAR AND S. K. CHAKRABORTY, Radiation effects on styrene-butadiene-ethylene-propylene diene monomer-multiple walled carbon nanotube nanocomposites: Vulcanization and characterization, Polymers for Advanced Technologies, 22(12)(2011)1888-1897.
    Canada
    International scientific journal
    2012
    Sharmin, N., Khan, R., Salmieri, S., Dussault, D., Bouchard, J., Lacroix, M. Mechanical and barrier properties of methylcellulose-based films grafted with trimethylolpropane trimethacrylate by gamma irradiation: effect of filling with cellulose nanocrystals, J. Sc. Technol. For Forest Products and Processes 2 (2012) 24-31.
    Canada
    International scientific journal
    2013
    Khan, R. A., Beck, S., Dussault, D., Salmieri, S., Bouchard, J., Lacroix, M. Mechanical and barrier properties of carbon nanotubes-reinforced PCL-based composite films: effect of gamma radiation. J. Appl. Polym. Sci. 127 (2013) 3962-9.
    France/Vietnam
    International scientific journal
    2014
    VO K. D. N., KOWANDY C., DUPONT L., NGUYEN Q. H., COQUERET X., Radiation synthesis of chitosan-stabilized gold nanoparticles: comparison between e(-) beam and gamma irradiation, Radiat. Phys. Chem. (2014), 94, 84-87
    Canada
    International scientific journal
    2014
    SALMIERI. S., ISLAM, F., KHAN, R. A., HOSSAIN, F. M., IBRAHIM, H. M. M., MIAO, C., HAMAD, W. Y., LACROIX, M., Antimicrobial nanocomposite films made of poly(lactic acid)-cellulose nanocrystals (PLA-CNC) in food applications. Part B: Effect of oregano essential oil release on the inactivation of Listeria monocytogenes in mixed vegetables. Cellulose. (2014) CELS-D-13-00484R2.
    India
    International scientific journal
    2014
    DUBEY, K. A., S. K. SINHA, Y. K. BHARDWAJ, L. PANICKER AND L. VARSHNEY, Carbon Black-Filled PE/PP/EPDM Blends: Phase Selective Localization of Carbon Black and EPDM-Induced Phase Stabilization." Polymer - Plastics Technology and Engineering 53(5) (2014) 442-450.
    Canada
    International scientific journal
    2012
    Khan, A., Huq, T., Khan, R.A., Dussault, D., Salmieri, S., Lacorix, M. Effect of ?-irradiation on the mechanical and barrier properties of HEMA grafted chitosan-based films. Rad. Phys. Chem., 81 (2012) 941-44.
    Pakistan
    International scientific journal
    2013
    KHAN, A., MEHMOOD, S., SHAFIQ, M., YASIN, T., AKHTER, Z., AHMAD, S. “Structural and Antimicrobial Properties of Irradiated Chitosan and its Complexes with Zinc”. Radiat Phys Chem, 91 (2013) 138–142
    Turkey
    International scientific journal
    2013
    KARSLI, N.,G., AYTA?, A., AKBULUT, M., DENIZ, V., GüVEN,O., “Effect of irradiated polypropylene compatibilizer on the properties of short carbon fiber reinforced polypropylene composites” Rad. Phys. Chem.,84(2013)74-78
    Italy
    International scientific journal
    2012
    DISPENZA C, SABATINO MA, NICONOV A, CHMIELEWSKA D, SPADARO G. E-beam crosslinked, biocompatible, functional hydrogels incorporating polyaniline nanoparticles. Radiat. Phys. Chem. 81 (2012) 1456-1459.
    Canada
    International scientific journal
    2010
    Khan, R., Salmieri, S., Dussault, D., Calderon, J.U., Kamal, M.R., Safrany, A., Lacroix, m. Production and Properties of Nanocellulose Reinforced Methylcellulose-Based Biodegradable Films. J. Agric. Food Chem., 58 (2010) 7878-7885
    Poland
    International scientific journal
    2013
    NOWICKI A, G. PRZYBYTNIAK, K. MIRKOWSKI, “Radiacyjne sieciowanie zywic epoksydowych z napelniaczami nanoweglowymi” in ?Modyfikacja polimerów. Stan i perspektywy w roku 2013” Ed. Ryszarda Stellera i Danuty Zuchowskiej, Wroclaw 2013, TEMPO s.c., ISBN 978-83-85520-19-0, p. 382-385.
    Turkey
    International scientific journal
    2012
    BAKAR, A., DE, V.V., ZEZIN, A.A., ABRAMCHUK, S.S., GüVEN,O., FELDMAN,V.I., “Spatial organization of a metal-polymer nanocomposite obtained by radiation-induced reduction of copper ions in the poly(allyl amin)-poly(acrylic acid)-Cu2+ system” Mendeleev Commun., 22(2012)211.
    Malaysia/Germany
    International scientific journal
    2013
    NIK GHAZALI NIK SALLEH, MOHD SOFIAN ALIAS, H-J.GL?SEL & R.MEHNERT. High performance radiation curable hybrid coatings, Radiation Physics and Chemistry Journal, 84 (2013) 70-73.
    Vietnam
    International scientific journal
    2013
    PHU, D.V., TRINH, N.T.A., DU, B.D., HIEN, N.Q., Gamma-irradiation synthesis of silver nanoparticles fixing in porous ceramic for application in water treatment, Vietnam Journal of Chemistry, 51 (2013) 653-657.
    India
    International scientific journal
    2011
    DUBEY, K. A., Y. K. BHARDWAJ, C. V. CHAUDHARI AND S. SABHARWAL, LDPE/EVA/PCR/MWNT nanocomposites: Radiation crosslinking and physicomechanical characteristics, Polymer Composites 32(5) (2011) 737-746
    Italy/Poland
    International scientific journal
    2014
    SPADARO G, ALESSI S, DISPENZA C, SABATINO MA, PITARRESI G, TUMINO D, PRYZBYTNIAK G, Radiation curing of carbon fibre composites. Radiat. Phys. Chem. 94 (2014) 14-17.
    India
    International scientific journal
    2012
    DUBEY, K. A., Y. K. BHARDWAJ, K. RAJKUMAR, L. PANICKER, C. V. CHAUDHARI, S. K. CHAKRABORTY AND S. SABHARWAL, Polychloroprene rubber/ethylene-propylene diene monomer/multiple walled carbon nanotube nanocomposites: Synergistic effects of radiation crosslinking and MWNT addition, Journal of Polymer Research 19(5)(2012).
    Malaysia
    International scientific journal
    2011
    NIK GHAZALI NIK SALLEH, MOHD FIRDAUS YHAYA, AZMAN HASSAN, AZNIZAM ABU BAKAR AND MUNIRAH MOKHTAR, Effect of radiation dosages on the properties of nanocomposite coatings. Radiation Physics and Chemistry Journal 80 (2011) 136-141.
    Vietnam
    International scientific journal
    2013
    QUOC, L.A, PHU, D.V, DUY, N.N, LANG, V.T.K, LAN, N.T.K., TRINH, N.T.A., HIEN, N.Q., Study on antibacterial activity (Escherichia coli) of porous ceramic fixed with silver nanoparticles, Nuclear Science and Technology, VINATOM, 3 (2013) 25-30.
    Italy/Poland
    International scientific journal
    2014
    TODARO S, SABATINO MA, WALO M, MANGIONE MR, BULONE D, DISPENZA C. Influence of gamma-irradiation on the thermally-induced mesoscopic gelation of degalactosylated xyloglucans. Radiat. Phys. Chem., 94 (2014) 245-248.
    France
    International scientific journal
    2014
    VO K. D. N., GUILLON E., DUPONT L., KOWANDY C., COQUERET X., Influence of Au(III) interactions with chitosan on gold nanoparticles formation, J. Phys Chem. (C) (2014), 118 (8), 4465–4474

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