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  • Radiation Treatment of Wastewater for Reuse with Particular Focus on Wastewaters Containing Organic Pollutants

    Closed for Proposals

    Project Type

    Coordinated Research Project

    Project Code

    F23029

    CRP

    1539

    Approved Date

    2 September 2010

    Project Status

    Closed

    Start Date

    15 November 2010

    Expected End Date

    15 November 2016

    Completed Date

    15 November 2016

    Description

    Chronic shortages of water in arid and semi-arid regions of the world and environmental policy regulations have stimulated the use of appropriate technologies in treating wastewater for reuse, for example, in urban irrigation, industrial uses (cooling, boilers, and laundry), gardens and parks, cleaning purposes, etc. Additionally, wastewater treatment is becoming ever more critical in large industrial centres due to diminishing water resources, increasing water disposal costs, and stricter discharge regulations that have lowered permissible contaminant levels in waste streams. Industrial effluents often carry chemical contaminants such as organics, petrochemicals, pesticides, dyes and heavy metal ions. The standard biological treatment processes commonly used for wastewater treatment are not capable of treating many of the complex organic chemicals that are found in varying quantities in the wastewaters (e.g. persistent organic pollutants, POPs). Radiation-initiated degradation of organics helps to transform various pollutants into less harmful substances or reduced to the levels below the permissible concentrations. Studies in several Member States (MS) have demonstrated the usefulness and efficiency of radiation technology for treatment of different organic pollutants. The lack of comparative data in pilot scale studies using radiation technique (alone or in combination with other methods) is the main problem in further utilization of this method for wastewater treatment. There is a need to study further the radiation effects, reliability and cost on specific group of organic pollutants in cooperation with other stakeholders who are involved in using other technologies.
    This CRP was formulated based on the recommendation of a consultants meeting held in 2008 and improved further in communication with external experts, two SAGNA members and discussed and revised in a meeting with the past-congress president of IWA-World Water Congress and a well known international expert from the Institute for Water Quality, Resources and Waste Management of Vienna University of Technology.
    The CRP intends (i) to study the effects, reliability and costs of room temperature radiation processing technology and determine the optimized radiation dose and procedures, in combination with other processes, to treat wastewater contaminated with low and high concentration of organic compounds; (ii) to validate analytical methods to characterize and evaluate effects of by-products in treated wastewaters; (iii) to obtain data on radiation method to treat wastewater with different concentration of organic pollutants and compare it with data from conventional and novel technologies; (iv) to develop guidelines for selection of areas where the radiation treatment has high potential for rendering treated wastewater suitable for industrial and irrigation purposes.
    The CRP teams envisaged to participate will comprise members drawn from industry (effluent managers), environmental regulatory authorities, and Members of International Water Association (IWA) apart from radiation technology and analytical scientists.

    Objectives

    To enhance Member States capacity in applying radiation technology in combination with other techniques for improving environmental safety aspects through effective treatment of wastewater contaminated with organic pollutants and support reuse of treated wastewater for urban irrigation and industrial purposes. This is in line with the objective of the project 2.5.2.5 to enhance Member States capacity in applying radiation technology for managing agricultural and industrial waste and effluents and decontamination of biological agents.

    Specific Objectives

    ? Study the effects, reliability and costs of room temperature radiation processing technology for specific groups of contaminants and specific application areas where the radiation technology is promising according to the assessment of existing knowledge.
    ? Assess the analytical methods to characterize and evaluate the effects on micro-pollutant reduction as well as impacts of radiation by-products in treated wastewaters (aquatic eco-toxicity studies)
    ? Determination of optimized radiation dose and procedures for different application cases, in combination with other pre- and post-treatment processes for contaminated wastewaters
    ? Develop guidelines for selection of areas where the radiation treatment has high potential for rendering treated wastewater suitable for industrial and irrigation purposes including boundary conditions for successful application.

    Impact

    The CRP was expected to enhance the capability of Member States in the use of radiation processing technology to treat wastewater contaminated with organic pollutants and support reuse of treated wastewater .
    This CRP investigated a wide variety of challenging pollutants in wastewaters originating from opium processing, cork industry, pharmaceutical industries, textile wastes, plastic industries, chemical fertilizers, municipal wastes, etc. The CRP focused on contemporary and emerging pollutants such as antibiotics, antidepressants, pharmaceuticals, soda wastes, reactive dyes, textile dyes, pesticides, oleo chemicals, endocrine disruptors, pathogens, PFOA, and enteric viruses. The ability to address this diverse set of pollutants with one core technology is noteworthy.
    The CRP resulted in development and testing of new ecotoxicity assays. The inclusion of ecotoxicity assays in determining the potential environmental toxicity of the radiation technology treated wastewater is also of significance. The rationale for including ecotoxicity as an end-point measurement of radiation treatment of this diversity of pollutants was novel. The choice of a particular ecotoxicity assay was based on the predicted radiation treatment byproducts.
    A variety of analytical methods were either adapted during the course of this CRP. These included pulse radiolysis with kinetic spectroscopic detection (for radiation chemistry), mammalian lung 8549 and mouse RAW 264.7 cells (for ecotoxicity measurements), ELISA, ZR-75 cancer cell lines and the yeast two-hybrid assay (for measuring estrogenic activity), analytical techniques (for directly measuring endocrine disruptors) and the DNA comet assay (to visualize microbial DNA damage). In addition to the analytical methods, considerable effort was spent towards designing and fabrication of hardware to facilitate these research needs.
    This CRP has allowed for a deeper understanding of the underlying chemistry that is occurring when different type of wastewater is exposed to varying ionizing radiation sources.
    There was significant progress made in the conceptual design and specifications of a movable/transportable eBeam treatment plant.
    A significant achievement of the CRP is that an industrial plant to treat 3000 m3 of textile dyeing wastewater has been built in China.
    Brazil has undertaken a programme to develop mobile electron accelerators to demonstrate on-site treatment of effluents from various industries.
    This CRP provided an outstanding opportunity for a number of individuals to be trained in various aspects of irradiation technology. This resulted in several Masters theses and Ph.D dissertations. Developing a deep science talent pool is critical to the success and sustainability of this technology. 64 peer-reviewed publications, 36conference proceedings, 4 patents and invention disclosures, 16 Ph.D. thesis and 20 M.S. thesis were published during the course of this CRP.

    Relevance

    Industrial effluents often carry chemical contaminants such as organics, petrochemicals, pesticides, dyes and heavy metal ions. The standard biological treatment processes commonly used for wastewater treatment are not capable of treating many of the complex organic chemicals that are found in varying quantities in the wastewaters (e.g. persistent organic pollutants, POPs). Another important problem arising is the increasing presence of pharmaceuticals and endocrine disruptors compounds in municipal wastewater entering into the receiving stream, for which new treatment techniques and procedures are needed to remove excreted drugs before releasing the effluent into public waterways or reuse. There is a need to develop effective and efficient technologies that help to transform various pollutants into less harmful substances or reduce their levels below the permissible concentrations. This CRP is a step in this direction.

    CRP Publications

    Hungary
    International Journal
    2012
    High-energy ionizing radiation initiated decomposition of acetovanillone, Radiat. Phys. Chem. 81 (2012) 1495-1498.
    USA
    International Journal
    2012
    Trimethoprim: Kinetic and Mechanistic Considerations in Photochemical Environmental Fate and AOP Treatment, Water Research 46 (2012) 1327-1336.
    Hungary
    Journal publication
    2016
    Radiat. Phys. Chem. (accepted).
    USA
    International Journal
    2012
    Recent advances in structure and reactivity of dissolved organic matter: Radiation chemistry of non-isolated natural organic matter and selected model compounds, Water Sci. Technol. 66 (2012) 1941-1949.
    Hungary
    Journal publication
    2015
    Reaction Kinetics, Mechanisms and Catalysis, 116 (2015) 95–103
    USA
    International Journal
    2012
    Kinetic model for the radical degradation of trihalonitromethane disinfection byproducts in water, Rad. Phys. Chem. 81 (2012) 1646–1652.
    Brazil
    Journal publication
    2016
    Environmental Science and Pollution Research (in press).
    Korea, Republic of
    Journal publication
    2015
    Journal of the Korean Physical Society (in press)
    Hungary
    International Journal
    2012
    Radiation degradation of pharmaceutical residues in water: chloramphenicol, Radiat. Phys. Chem. 81 (2012) 1489-1494.
    Hungary
    International Journal
    2012
    Mineralization of aqueous phenolate solutions: a combination of irradiation treatment and wet oxidation, Radiat. Phys. Chem. 81 (2012) 1484-1488
    China
    Journal Publication
    2011
    Pretreatment of paper mill effluent by a combined process of coagulation and ionizing irradiation, Environmental Science.32 6 (2011) 1638-1643. (in Chinese)
    Korea, Republic of
    M.Sc. Thesis
    2014
    YUN, J.H., 2014, Development of film dosimetry system, Dept. of Industrial Application, Chungnam University.
    Poland
    Journal publication
    2013
    Radiation Physics and Chemistry, 83 (2013) 86–89.
    Italy
    M.Sc. Thesis
    2015
    Montanari, S., 2015, Sinergy of physical-chemical processes for the requalification of water contaminated by organic matter, Department of Industrial Chemistry, Bologna University.
    Hungary
    Journal publication
    2014
    Radiation Physics and Chemistry, 96 (2014) 120–134.
    Hungary
    Journal publication
    2015
    Science of the Total Environment (submited).
    Hungary
    Journal publication
    2016
    Radiat. Phys. Chem. (accepted).
    Hungary
    International Journal
    2011
    Mechanism of azo dye degradation in Advanced Oxidation Processes: Radiolytic degradation of Sulfanilic Acid Azochromotrop and its parent compounds in aqueous solution, Radiation Physics and Chemistry, 80 (2011) 462-470.
    Hungary
    Journal publication
    2016
    J. Phys Chem. (submitted)
    Hungary
    Ph.D. thesis
    2016
    Krisztina Kovacs, Radiation induced degradation of fenilurea herbicides (under preparation)
    USA
    International Journal
    2012
    Comparing Extraction Buffers to Identify Optimal Method to Extract Somatic Coliphages from Sewage Sludges, Bioresources Technol. (2012). (in press)
    Korea
    Journal Publication
    2011
    Electron beam flue gas treatment for thermal power station ‘Sviloza’ AD in Bulgaria, Journal of the Korean Physical Society 59 6 (2011) 3494-3498.
    Portugal
    Ph. D. Thesis
    2012
    Application of Ionizing Radiation to Persistent Organic Pollutants Decomposition, PhD thesis on Technological Chemistry, Supervisor: Leal, J.P., (IST/ITN, CQB/FCUL), Botelho, M.L., (IST/ITN). (Defence in December 2012)
    China
    Journal publication
    2014
    Nuclear Science and Techniques (accepted)
    Brazil
    M.Sc. Thesis
    2015
    Flavio Tominaga, Voltaren in water and wastewater toxic effects when treated by electron beam irradiation, Universidade de S?o Paulo. (in progress)
    Italy
    Journal publication
    2015
    . CLEAN-Air, soil water (submitted).
    China
    Journal publication
    2014
    Acta Scientiae Circumstantiae, 34 (2014) 60–66. (in Chinese)
    Hungary
    Journal publication
    2014
    Israel Journal of Chemistry 54 (2014) 233–241.
    USA
    Ph.D. thesis
    2015
    A-S C. HIEKE, 2015, Investigating the inactivation, physiological characteristics and transcriptomic responses of bacteria exposed to ionizing radiation,
    USA
    International Journal
    2012
    Mechanistic considerations for the degradation of methyl tert-butyl ether (MTBE) by sonolysis: Effect of argon vs. oxygen saturated solutions, UltrasonicsSonochemistry 19 (2012) 959-968.
    USA
    International Journal
    2012
    Photochemical Fate of Beta-blockers in NOM Enriched Waters, Sci. Total Environ. 426 (2012) 289-295.
    China
    Journal Publication
    2011
    The advanced treatment of secondary biological paper mill effluent by ionizing irradiation, Acta Scientiae Circumstantiae. 31 10 (2011) 2169-2173. (in Chinese)
    Korea, Republic of
    Journal publication
    2015
    Journal of hazardous Materials (2015).
    USA
    International Journal
    in print
    Hydroxyl Radical Oxidation of Cylindrospermopsin (Cyanobacterial Toxin) and its Role in the Photochemical Transformation, Environ. Sci. Technol. (in press)
    Hungary
    Ph.D. thesis
    2015
    Renáta Homlok, 2015, Relation between chemical structure and degradability in advanced oxidation processes
    Hungary
    Journal publication
    2014
    Radiation Physics and Chemistry 97 (2014) 239–245.
    Korea
    Journal Publication
    2011
    High power accelerators for environmental applications, Journal of the Korean Physical Society 59 6 (2011) 3485-3488.
    Hungary
    Ph.D. thesis
    2016
    Laszlo Szabo, Free radical chemistry of penicillin derivatives (under preparation)
    USA
    International Journal
    2012
    Photochemical Fate of Antidepressant Pharmaceuticals in Simulated Natural Waters, J. Hazardous Materials 217-281 (2012) 382-390.
    Hungary
    M.Sc. Thesis
    2014
    Gyuri Sagi, 2014, High-energy ionizing radiation induce decomposition of sulphametasol.
    Portugal
    International Journal
    2012
    Effect of ionizing radiation on antioxidant compounds present in cork wastewater, Water Sci. (2012)Technol.doi:10.2166/wst.2012.544.
    China
    International Journal
    2011
    Dechlorination process of chlorinated organic compounds by ionizing irradiation in aqueous solutions, J. Radiat. Res. Radiat. Process. 29 6 (2011) 321-325.
    Hungary
    Ph.D. thesis
    2014
    Erzsébet Illés, 2014, Application of radiolysis and other AOP to the decomposition of non-steroidal inflammatory drugs
    Hungary
    Ph.D. thesis
    2016
    Gyuri Sagi, High-energy ionizing radiation induce decomposition of sulphonamide type antibiotics (under preparation)
    Korea, Republic of
    M.Sc. Thesis
    2014
    LEE, J.H., 2014, Development of conversion system of X-ray from electron beam, Dept. of Industrial Application, Chungnam University.
    Korea, Republic of
    Journal publication
    2012
    Journal of Hazardous Materials (2012).
    Hungary
    Journal publication
    2013
    Chemosphere 92 1579 (2013)
    Egypt
    M.Sc. Thesis
    2015
    Shimaa ElBakry, 2015, Radiation Synthesis of Imprinted Polymers for Waste Water Treatment, Faculty of Science (for Girls), AlAzhar University
    China
    International Journal
    2012
    Comparison of different chlorophenols degradation in aqueous solutions by gamma irradiation under reducing conditions, Radiation Physics and Chemistry. 81 (2012) 1629-1633.
    USA
    Journal publication
    2015
    Radiation Physics and Chemistry 110 (2015) 38–41
    Egypt
    Ph.D. thesis
    2015
    Noha Degheidy, 2015, Radiation Synthesis of Polyaniline Based Compounds and Their Potential Applications Faculty of Science, Ain Shams University
    Korea, Republic of
    M.Sc. Thesis
    2014
    KIM, S.M., 2014, Comparison of X-ray conversion system, Dept. of Industrial Application, Chungnam University.
    Hungary
    International Journal
    2012
    Radiolysis of paracetamol in dilute aqueous solution, Radiat. Phys. Chem. 81 (2012) 1503-1507.
    Japan
    Journal publication
    2012
    Free Radical Research, 46 (2012) 861–871
    Hungary
    Journal publication
    2016
    Int. J. Mol. Sci. (accepted)
    Korea
    International Journal
    2012
    Operation of industrial-scale electron beam wastewater treatment plant, Radiation Physics and Chemistry 81 (2012) 1475-1478.
    China
    Journal Publication
    2012
    Comparison study of wastewater disinfection by UV, Ozone and ionizing irradiation, Journal of Wuhan University of Technology 34 5 (2012) 82-86. (in Chinese)
    Hungary
    Journal publication
    2013
    Radiation Physics and Chemistry 87 (2013) 82–87.
    Korea
    Journal Publication
    2011
    Application of electron accelerator for the treatment of wastewater from textile dying industries, Journal of the Korean Physical Society 59 6 (2011) 3489-3493.
    Italy
    Journal publication
    2015
    . La Chimica e l''Industria (2015) (in press).
    Hungary
    International Journal
    2012
    Ionizing radiation induced reactions of 2,6-dichloroaniline in dilute aqueous solution, Radiat. Phys. Chem. 81 (2012) 1499-1502.
    Hungary
    International Journal
    2011
    Elimination of diclofenac from wastewater using irradiation technology, Chemosphere 85 (2011) 603-608.
    Hungary
    M.Sc. Thesis
    2014
    Laszlo Szabo, 2014, A comparison of the radiation induced degradation of salicilyc acid derivatives in aqueous solutions.
    Brazil
    M.Sc. Thesis
    2014
    Vanessa Honda Ogihara-Silva, 2014, Assessment of toxicity and degradation of fluoxetine in water solution and sewage when treated by electron beam irradiation, Universidade de S?o Paulo.
    Korea
    Journal Publication
    2011
    Industrial Applications of e-beam accelerators in Korea, Journal of the Korean Physical Society 60 2 (2012).
    China
    Journal publication
    2015
    Radiat. Phys. Chem. 108 (2015) 102–105.
    USA
    International Journal
    2012
    Oxidative Degradation of Alternative Gasoline Oxygenates in Aqueous Solution by Ultrasonic Irradiation: Mechanistic Study, Sci. Total Environ. 430 (2012) 246–259.
    Italy
    Journal publication
    2014
    Environmental Science and Pollution Research International, 21 (2014) 12135 – 12142.
    Brazil
    M.Sc. Thesis
    2015
    Nathalia Boiani, Toxicity effects of propanolol in water and wastewater treated by electron beam irradiation, Universidade de S?o Paulo. (in progress)
    Hungary
    Journal publication
    2016
    Radiat. Phys. Chem. (accepted).
    Hungary
    International Journal
    2012
    Radiation induced degradation of ketoprofen in dilute aqueous solution, Radiat. Phys. Chem. 81 (2012) 1479-1483.
    Italy
    Ph.D. thesis
    2015
    Micaela Saracino, 2015, Advanced oxidation processes for water remediation, Department of Industrial Chemistry, University of Bologna.
    Turkey
    Journal publication
    2015
    Radiochimica Acta. 103 (2) (2015) 137–147.
    Korea, Republic of
    Journal publication
    2015
    Journal of Industrial Radiation Association 102 (2015) 583–587
    Korea
    Journal Publication
    2011
    Electron Beam Technology in Korean Industries, Journal of the Korean Physical Society 59 2 (2011) 542-545.
    Hungary
    M.Sc. Thesis
    2015
    Mate Mihalovics, 2015, Investigation of radical transfer reactions during advanced oxidation processes.
    China
    Journal publication
    2016
    Radiat. Phys. Chem. 119 (2016) 194–199.
    China
    Journal publication
    2016
    Radiat. Phys. Chem. (accepted).
    Hungary
    Journal publication
    2014
    . Radiat. Phys. Chem. 102 (2014) 72–78.
    Brazil
    M.Sc. Thesis
    2015
    Aline Vieira de Moraes, 2015, Color and toxicity removal of textile effluents treated by electron beam irradiation, Universidade de S?o Paulo.
    Egypt
    Journal publication
    2015
    Desalination and Water Treatment (2015) 1–12.
    Hungary
    Journal publication
    2015
    Journal of Pharmaceutical and Biomedical Analysis. Special issue on Pharmaceuticals in Environmental Media, Biota, Food Commodities and Work Place: Analytical Approaches. 106 (2015) 52–60

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